Advances in Microwave Denitration for Mixed Uranium-Plutonium Fuel

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Researchers at the Vernadsky Institute of Geochemistry and Analytical Chemistry, part of the Russian Academy of Sciences, have unveiled a new approach to producing mixed uranium and plutonium nuclear fuel with microwave radiation. According to RIA Novosti, this technique holds the potential to nearly eradicate the creation of dangerous liquid radioactive waste during the fuel production process.

Rosatom State Corporation is actively integrating technologies necessary for a transition to a competitive energy system built on a closed nuclear fuel cycle that uses mixed uranium plutonium fuel. The closed fuel cycle offers a solution to the persistent challenge of limited natural uranium reserves. Yet experts point out that the traditional method for making the mixed fuel, which relies on mechanically blending uranium dioxide with plutonium dioxide powders, carries certain drawbacks that concern safety and efficiency.

Sergey Vinokurov, Deputy Director of Research at GEOKHI, highlighted that the mechanical mixing approach can lead to locally uneven fuel combustion because achieving a perfectly uniform distribution of plutonium within uranium dioxide is difficult. The process also presents risks such as the potential separation of pure plutonium, which conflicts with nonproliferation goals for fissile materials. Additionally, fallout washing in this method can generate substantial volumes of liquid radioactive waste, creating waste management challenges that require careful handling and disposal strategies.

Against this backdrop, GEOKHI researchers proposed an alternative route to produce a mixed oxide fuel by combining uranium and plutonium by microwave denitration. This method leverages the dielectric characteristics of uranium, which can strongly absorb microwave energy and heat to very high temperatures. Through this heating mechanism, a more homogeneous mixture of uranium and plutonium dioxide can be achieved, and the resulting material can be formed into ceramic fuel pellets ready for use in reactors.

A key advantage of the microwave denitration process is its ability to proceed without introducing additional chemical reagents. This reduces the risk of introducing extraneous contaminants into the fuel and contributes to a safer overall production environment. Microwave chambers can be positioned behind protective shielding, while the microwave generators and electronic control systems can be situated in controlled areas that minimize exposure to personnel. This layout supports stringent safety protocols and helps safeguard workers during operation.

In this broader discussion, the focus remains on improving fuel quality and safety while supporting the goal of a sustainable, low-waste nuclear fuel cycle. The proposed microwave-based approach aims to deliver a more uniform fuel product, with fewer waste streams, and a production workflow that aligns with modern safety standards and nonproliferation requirements. The work at GEOKHI underscores ongoing efforts to refine fuel fabrication technologies and to explore methods that harmonize performance, safety, and environmental stewardship in nuclear energy systems.

Historically, researchers in related fields have explored where certain processes perform best under shielding and containment conditions, including considerations around the potential for atmospheric or explosive release during testing. While these historical notes illustrate the importance of safety and containment in nuclear research, the current developments emphasize controlled, well-monitored fabrication environments designed to minimize risk and maximize predictability in fuel manufacture.

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